Diphenyldichlorophosphonium trichloride-chlorine solvate 1:1, [PPh2Cl2]+Cl(3)(-).Cl2: an ionic form of diphenyltrichlorophosphorane. Crystal structures of [PPh2Cl2]+Cl(3)(-).Cl2 and [(PPh2Cl2)+]2[InCl5](2-).
Identifieur interne : 003352 ( Main/Exploration ); précédent : 003351; suivant : 003353Diphenyldichlorophosphonium trichloride-chlorine solvate 1:1, [PPh2Cl2]+Cl(3)(-).Cl2: an ionic form of diphenyltrichlorophosphorane. Crystal structures of [PPh2Cl2]+Cl(3)(-).Cl2 and [(PPh2Cl2)+]2[InCl5](2-).
Auteurs : RBID : pubmed:12767197Abstract
An ionic form of diphenyltrichlorophosphorane, namely, diphenyldichlorophosphonium trichloride isolated as a dichlorine solvate (1), was obtained by treating PPh(2)Cl(3) with excess chlorine. The identity of this species was established by single-crystal X-ray analysis and (31)P, (1)H, and (35)Cl NMR and Raman spectra. Bis(diphenyldichlorophosphonium) pentachloroindate (2) was obtained by the reaction of diphenyltrichlorophosphorane with indium trichloride in dichloromethane for comparison purposes. Its identity was determined by (31)P NMR spectra and single-crystal X-ray analysis.
DOI: 10.1021/ic034091n
PubMed: 12767197
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Diphenyldichlorophosphonium trichloride-chlorine solvate 1:1, [PPh2Cl2]+Cl(3)(-).Cl2: an ionic form of diphenyltrichlorophosphorane. Crystal structures of [PPh2Cl2]+Cl(3)(-).Cl2 and [(PPh2Cl2)+]2[InCl5](2-).</title><author><name sortKey="Taraba, Jan" uniqKey="Taraba J">Jan Taraba</name><affiliation wicri:level="1"><nlm:affiliation>Department of Inorganic Chemistry, Masaryk University, Kotlarska 2, 611 37 Brno, Czech Republic.</nlm:affiliation><country xml:lang="fr">République tchèque</country><wicri:regionArea>Department of Inorganic Chemistry, Masaryk University, Kotlarska 2, 611 37 Brno</wicri:regionArea></affiliation></author><author><name sortKey="Zak, Zdirad" uniqKey="Zak Z">Zdirad Zak</name></author></titleStmt><publicationStmt><date when="2003">2003</date><idno type="RBID">pubmed:12767197</idno><idno type="pmid">12767197</idno><idno type="doi">10.1021/ic034091n</idno><idno type="wicri:Area/Main/Corpus">003480</idno><idno type="wicri:Area/Main/Curation">003480</idno><idno type="wicri:Area/Main/Exploration">003352</idno></publicationStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">An ionic form of diphenyltrichlorophosphorane, namely, diphenyldichlorophosphonium trichloride isolated as a dichlorine solvate (1), was obtained by treating PPh(2)Cl(3) with excess chlorine. The identity of this species was established by single-crystal X-ray analysis and (31)P, (1)H, and (35)Cl NMR and Raman spectra. Bis(diphenyldichlorophosphonium) pentachloroindate (2) was obtained by the reaction of diphenyltrichlorophosphorane with indium trichloride in dichloromethane for comparison purposes. Its identity was determined by (31)P NMR spectra and single-crystal X-ray analysis.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="PubMed-not-MEDLINE"><PMID Version="1">12767197</PMID><DateCreated><Year>2003</Year><Month>05</Month><Day>27</Day></DateCreated><DateCompleted><Year>2004</Year><Month>01</Month><Day>05</Day></DateCompleted><Article PubModel="Print"><Journal><ISSN IssnType="Print">0020-1669</ISSN><JournalIssue CitedMedium="Print"><Volume>42</Volume><Issue>11</Issue><PubDate><Year>2003</Year><Month>Jun</Month><Day>2</Day></PubDate></JournalIssue><Title>Inorganic chemistry</Title><ISOAbbreviation>Inorg Chem</ISOAbbreviation></Journal><ArticleTitle>Diphenyldichlorophosphonium trichloride-chlorine solvate 1:1, [PPh2Cl2]+Cl(3)(-).Cl2: an ionic form of diphenyltrichlorophosphorane. Crystal structures of [PPh2Cl2]+Cl(3)(-).Cl2 and [(PPh2Cl2)+]2[InCl5](2-).</ArticleTitle><Pagination><MedlinePgn>3591-4</MedlinePgn></Pagination><Abstract><AbstractText>An ionic form of diphenyltrichlorophosphorane, namely, diphenyldichlorophosphonium trichloride isolated as a dichlorine solvate (1), was obtained by treating PPh(2)Cl(3) with excess chlorine. The identity of this species was established by single-crystal X-ray analysis and (31)P, (1)H, and (35)Cl NMR and Raman spectra. Bis(diphenyldichlorophosphonium) pentachloroindate (2) was obtained by the reaction of diphenyltrichlorophosphorane with indium trichloride in dichloromethane for comparison purposes. Its identity was determined by (31)P NMR spectra and single-crystal X-ray analysis.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Taraba</LastName><ForeName>Jan</ForeName><Initials>J</Initials><Affiliation>Department of Inorganic Chemistry, Masaryk University, Kotlarska 2, 611 37 Brno, Czech Republic.</Affiliation></Author><Author ValidYN="Y"><LastName>Zak</LastName><ForeName>Zdirad</ForeName><Initials>Z</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType>Journal Article</PublicationType></PublicationTypeList></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>Inorg Chem</MedlineTA><NlmUniqueID>0366543</NlmUniqueID><ISSNLinking>0020-1669</ISSNLinking></MedlineJournalInfo></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="pubmed"><Year>2003</Year><Month>5</Month><Day>28</Day><Hour>5</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2003</Year><Month>5</Month><Day>28</Day><Hour>5</Hour><Minute>1</Minute></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2003</Year><Month>5</Month><Day>28</Day><Hour>5</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">12767197</ArticleId><ArticleId IdType="doi">10.1021/ic034091n</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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